(1H-1,2,4-Triazol-1-yl)methyl 2-(2,4-dichlorophenoxy)acetate
نویسندگان
چکیده
In the title compound, C(11)H(9)Cl(2)N(3)O(3), the triazole and benzene rings are roughly parallel to one another [dihedral angle = 4.99 (2)°] because the C-O-C-C-O chain that links the two rings is folded [O-C-C-O = 8.60 (2)°] rather than fully extended. In the crystal, weak inter-molecular C-H⋯N and C-H⋯O inter-actions are present, and π-π inter-actions are indicated by the short distances [3.749 (3) Å] between the centroids of the triazole and benzene rings.
منابع مشابه
Simple and efficient synthesis of racemic 2-(tert-butoxycarbon-ylamino)-2-methyl-3-(1H-1,2,4-triazol-1-yl)propanoic acid, a new derivative of β-(1,2,4-triazol-1-yl)alanine.
A simple synthetic approach to racemic N-tert-butyloxycarbonyl-2-methyl-3-(1H-1,2,4-triazol-1-yl)alanine (5) in four steps and 68% overall yield starting from oxazoline derivative 1 is reported. This synthesis involves the alkylation of 1H-1,2,4-triazole with an O-tosyloxazoline derivative, followed by an oxazoline ring-opening reaction and oxidation of the N-protected β‑aminoalcohol by potassi...
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